Product ID:TOLUOL, METHYLBENZENE, TX0745
MSDS Date:04/05/1995
FSC:6810
NIIN:00N018306
MSDS Number: CBBBR

EM SCIENCE

480 DEMOCRAT RD
GIBBSTOWN, NJ 08027
US

Emergency Phone: 800-424-9300 (CHEMTREC)

Info Phone: 609-354-9200

Cage: DO242

EM SCIENCE

70 GIBBSTOWN, NJ 08927 US

Telephone: 800-424-9300 (CHEMTREC)

Cage: DO242

TOLUENE (SARA 313) (CERCLA)

CAS: 108-88-3

RTECS: XS5250000

Fraction By Weight: 100%

OSHA PEL 200 PPM

ACGIH TLV: 50 PPM

EPA Report Quantity: 1000 LBS

DOT Report Quantity: 1000 LBS

LD50 LC50 Mixture:LD50 (ORAL RAT): 636 MG/KG.
Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES
Reports of Carcinogenicity:NTP:NO IARC:NO OSHA:NO
Health Hazards Acute and Chronic:ACUTE: HARMFUL/FATAL IF SWALLOWED.
VAPS HARMFUL IF INHALED. SYMPS: HDCH, DIZZ, HALLUCINATIONS,
DISTORTED PERCEPTIONS, CHANGES IN MOTOR ACTIVITY, NAUS, DIARR, RESP
IRRIT, CNS DEPRESS, UNCON, LIVER, KID NEY & LUNG DMG. CONT CAN
CAUSE SEV EYE IRRIT. MAY CAUSE SKIN IRRIT. TOX FINDINGS: TESTS ON
LAB ANIMALS (EFTS OF OVEREXP)
Explanation of Carcinogenicity:NOT RELEVANT.
Effects of Overexposure:HLTH HAZ: INDICATE MATL MAY PRDCE ADVERSE
MUTAGENIC & REPRO EFTS. CHRONIC: TOLUENE APPEARS ON THE NAVY LIST
OF OCCUP CHEM REPRO HAZ. SEEK CONSULTATION FROM APPROP HLTH
PROFESSIONALS CONCERNING LATEST HAZ LIST INFO & SAFE HNDLG & EXPOS
INFO.
Medical Cond Aggravated by Exposure:RESPIRATORY, LIVER AND KIDNEY
CONDITIONS.

First Aid:GET MEDICAL ASSISTANCE FOR ALL CASES OF OVEREXPOSURE. EYES:
IMMEDIATELY FLUSH THOROUGHLY WITH WATER FOR AT LEAST 15 MINUTES.
SKIN: WASH THOROUGHLY WITH SOAP AND WATER. INHALATION: REMOVE TO
FRESH AIR. GIVE ARTIFICIAL RESPIRATION IF BREATHING HAS STOPPED.
INGESTION: CALL MD IMMEDIATELY. ONLY INDUCE VOMITING AT THE
INSTRUCTIONS OF MD. NEVER GIVE ANYTHING BY MOUTH TO AN UNCONSCIOUS
PERSON.

Flash Point Method:TCC
Flash Point:40.0F,4.4C
Lower Limits:1.30%
Upper Limits:7.10%
Extinguishing Media:USE DRY CHEMICAL, FOAM, CARBON DIOXIDE, WATER SPRAY
TO COOL EXPOSED CONTAINERS.
Fire Fighting Procedures:WEAR NIOSH/MSHA APPROVED SCBA & FULL
PROTECTIVE EQUIPMENT .
Unusual Fire/Explosion Hazard:DANGEROUS FIRE AND EXPLOSION HAZARD.
VAPOR CAN TRAVEL DISTANCES TO IGNITION SOURCE AND FLASH BACK.

Spill Release Procedures:EVACUATE AREA OF ALL UNNEC PERS. WEAR SUITABLE
PROT EQUIP LISTED UNDER "CTL MEASURES". ELIM ANY IGNIT SOURCES
UNTIL AREA IS DETERMINED TO BE FREE FROM EXPLO/FIRE HAZ. CONTAIN
RELEASE & ELIM ITS SOURCE , IF THIS CAN BE DONE W/OUT RISK. TAKE UP
& CONTAINERIZE FOR PROPER DISP AS DESCRIBED UNDER "WASTE DISP
METH". COMPLY W/FED, STATE & LOC REGS ON REPORTING RELEASES. REFER
TO REGULATORY INFO (SUP DAT)
Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER.

Handling and Storage Precautions:KEEP CONTAINER CLOSED. STORE IN A COOL
AREA AWAY FROM IGNITION SOURCES AND OXIDIZERS. DO NOT BREATHE VAPOR
OR SOLUTION MIST.
Other Precautions:DO NOT GET IN EYES, ON SKIN, OR ON CLOTHING. RETAINED
RESIDUE MAY MAKE EMPTY CONTAINERS HAZARDOUS; USE CAUTION!
ELECTRICALLY GROUND ALL EQUIPMENT WHEN HANDLING THIS PRODUCT.

Respiratory Protection:IF WORKPLACE EXPOS LIM OF PROD/ANY COMPONENT IS
EXCEEDED (SEE TLV/PEL), A NIOSH/MSHA APPRVD AIR SUPP RESP IS
ADVISED IN ABSENCE OF PROPER ENVIRON CTL. OSHA REGS ALSO PERMIT
OTHER NIOSH/MSHA APPRVD RES PS (NEG PRESS TYPE) UNDER SPECIFIED
CNDTNS (SEE YOUR SAFETY EQUIP SUPPLIER). ENGINEERING AND/OR
ADMINISTRATIVE CONTROLS SHOULD BE IMPLEMENTED TO REDUCE EXPOS.
Ventilation:MATERIAL SHOULD BE HANDLED OR TRANSFERRED IN AN APPROVED
FUME HOOD OR WITH ADEQUATE VENTILATION.
Protective Gloves:VITON, POLYURETHANE, OR EQUIVALENT.
Eye Protection:ANSI APPRVD CHEM WORKERS GOGGS .
Other Protective Equipment:EMERGENCY EYEWASH & DELUGE SHOWER MEETING
ANSI DESIGN CRITERIA .
Work Hygienic Practices:WASH THOROUGHLY AFTER HANDLING. DO NOT TAKE
INTERNALLY. SAFETY EQUIPMENT SHOULD BE READILY AVAILABLE.
Supplemental Safety and Health
SPILL PROC: FOR REPORTABLE QTY & OTHER REGULATORY DATA. EM SCIENCE
RECOMMENDS SPILL-X ABSORB FOR VARIOUS TYPES OF SPILLS. ADDNL INFO
ON SPILL-X PRODS CAN BE PROVIDED THROUGH THE EM SCIENCE TECHNICAL S
ERVICE DEPARTMENT (609) 354-9200. THE FOLLOWING EM SCIENCE SPILL-X
ABSORBENT IS RECOMMENDED FOR THIS (OTHER INFO)

Boiling Pt:B.P. Text:231F,111C
Melt/Freeze Pt:M.P/F.P Text:-139F,-95C
Vapor Pres:21.86
Vapor Density:3.2
Spec Gravity:0.866 (H*2O=1)
Evaporation Rate & Reference:2.24 (BUTYL ACETATE=1)
Solubility in Water:INSOLUBLE
Appearance and Odor:CLEAR, COLORLESS LIQUID, WITH AROMATIC ODOR
Percent Volatiles by Volume:>99

Stability Indicator/Materials to Avoid:YES
OXIDIZERS, STRONG MINERAL ACIDS.
Stability Condition to Avoid:HEAT; CONTACT WITH IGNITION SOURCE.
Hazardous Decomposition Products:CO*X, HYDROCARBONS.

Waste Disposal Methods:INCINERATION, FUELS BLENDING OR RECYCLE. CONTACT
YOUR LOCAL PERMITTED WASTE DISPOSAL SITE (TSD) FOR PERMISSIBLE
TREATMENT SITES. ALWAYS CONTACT A PERMITTED WASTE DISPOSER (TSD) TO
ASSURE COMPLIANCE W/ ALL CURRENT LOCAL, STATE AND FEDERAL
REGULATIONS.

Disclaimer (provided with this information by the compiling agencies):
This information is formulated for use by elements of the Department
of Defense. The United States of America in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. Any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.